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化学・生命化学専攻

個別データ

 分類論文発表
 発行年月2018/02/02
 タイトルSynthesis and Reaction of ortho-Benzoquinone Monohemiaminals
 著者齋藤絵美、松本悠理、〇中村章彦、滑侑紀、〇中田雅久
 ジャーナル名Organic Letters
 刊 - 号 - ページ20 - 3 - 692-695
 概要The preparation and reactions of ortho-benzoquinone monohemiaminals are described. The oxidative dearomatization of phenols bearing amino alcohol groups induced N-cyclization to afford ortho-benzoquinone monohemiaminals. The N-cyclization stereoselectively affords the product when a chiral amino alcohol is used as the substituent. The chiral ortho-benzoquinone monohemiaminal undergoes stereoselective Diels–Alder reactions with electron-deficient alkenes, as expected, confirming the promising utility of ortho-benzoquinone monohemiaminals.
 参考web http://pubs.acs.org/doi/10.1021/acs.orglett.7b03824
 指導教員中田 雅久