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分類 | 論文発表 | |
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発行年月 | 2018/02/02 | |
タイトル | Synthesis and Reaction of ortho-Benzoquinone Monohemiaminals | |
著者 | 齋藤絵美、松本悠理、〇中村章彦、滑侑紀、〇中田雅久 | |
ジャーナル名 | Organic Letters | |
刊 - 号 - ページ | 20 - 3 - 692-695 | |
概要 | The preparation and reactions of ortho-benzoquinone monohemiaminals are described. The oxidative dearomatization of phenols bearing amino alcohol groups induced N-cyclization to afford ortho-benzoquinone monohemiaminals. The N-cyclization stereoselectively affords the product when a chiral amino alcohol is used as the substituent. The chiral ortho-benzoquinone monohemiaminal undergoes stereoselective Diels–Alder reactions with electron-deficient alkenes, as expected, confirming the promising utility of ortho-benzoquinone monohemiaminals. | |
参考web | http://pubs.acs.org/doi/10.1021/acs.orglett.7b03824 | |
指導教員 | 中田 雅久 |